Technological watch

Coal gasification fine slag is a by-product of the entrained-flow gasifier, which has caused some environmental pollution. Through acid dissolution and calcination at different temperatures, mesoporous spherical silica/porous carbon composite filler was prepared using coal gasification fine slag. The particle size and specific surface area of the composite filler decreased with the decrease of unburned carbon content. The analysis of X-ray photoelectron spectroscopy (XPS) indicated the decrease of oxygen-containing functional groups and the increase of C–C groups with the decrease of the content of carbon. The effects of mesoporous spherical silica/porous carbon with different carbon content on the comprehensive properties of filled polypropylene (PP) were studied. The tensile strength and interface interaction increased at first and then decreased with the decrease of carbon content, due to the synergistic effect of mesoporous spherical silica and rough amorphous carbon. The scanning electron microscope showed that the composite filler with the carbon content of 14.47 wt.% at the calcination temperature of 450 °C had the best compatibility with the matrix. Thermodynamic analysis of the PP composites indicated that thermal insulation properties and thermal stability improved with the incorporation of the composite filler. Differential scanning calorimetry (DSC) testing indicated the highest crystallinity of the matrix corresponding to the best comprehensive performances of the composites. XRD patterns revealed that the cooperation of fillers brought characteristic peaks and did not change the primary crystal structure of PP. Simultaneously, heavy calcium powders (CC) were used as comparative fillers, and the overall properties of the PP composites filled with the composite filler were better compared to those of the CC-filled PP composite. The results illustrated that mesoporous spherical silica/porous carbon particles can completely replace CC used in the PP composites, which can be used in auto bumpers, plastic pipes, display cases, and car air deflectors. The CGFS can be processed into a plastic filler for substituting heavy calcium powder particles, which can solve the environmental pollution caused by the accumulation of solid waste.

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